4-3. 3_Ps_GenL
Polymer Class are same as key of Ps_GenL.
The alocated number of polymerization reaction are key of Ps_rxnL.
The numbers within the square brackets in the monomer class correspond to the values of mon_dic and key of mon_dic_inv.
Correspondence Table of Numbers and Content
Table 4-8. For the function “bipolym”
Defined polymer class, assigned polymerization reactions and corresponding monomer classes.
Polymer Class |
Polymerization Reaction |
Monomer Class 1 |
Monomer Class 2 |
Reaction Type |
Product |
|---|---|---|---|---|---|
Polyolefin |
1 |
Vinyl [1] |
Addition Chain Polymerization |
Homopolymer |
|
Polyolefin |
3 |
Cyclic Olefin [3] |
Addition Chain Polymerization |
Homopolymer |
|
Polyolefin |
101 |
Vinyl [1] |
Vinyl [1] |
Addition Chain Polymerization |
Alternating copolymer |
Polyolefin |
102 |
Vinyl [1] |
Cyclic Olefin [3] |
Addition Chain Polymerization |
Alternating copolymer |
Polyolefin |
103 |
Cyclic Olefin [3] |
Cyclic Olefin [3] |
Addition Chain Polymerization |
Alternating copolymer |
Polyester |
4 |
Lactone [4] |
Ring-Opening Chain Polymerization |
Homopolymer |
|
Polyester |
6 |
Hydroxy Carboxylic Acid [6] |
Polycondensation |
Homopolymer |
|
Polyester |
105 |
Hydroxy Carboxylic Acid [6] |
Hydroxy Carboxylic Acid [6] |
Polycondensation |
Alternating copolymer |
Polyester |
104 |
Di/Polycarboxylic Acid [52] |
Di/Polyol [53] |
Polycondensation |
Homopolymer |
Polyester (polycarbonate) |
106 |
Di/Polyol [53] |
Carbon Monoxide [10] |
Polycondensation |
Homopolymer |
Polyester |
112 |
Cyclic Anhydride [9] |
Epoxide [2] |
Ring-Opening Chain Polymerization |
Homopolymer |
Polyether |
2 |
Epoxide [2] |
Ring-Opening Chain Polymerization |
Homopolymer |
|
Polyether |
8 |
Hindered Phenol [8] |
Polycondensation |
Homopolymer |
|
Polyetherh |
114 |
Bis(p-Halogenated Aryl)Sulfone [12] |
Di/Polyol (Without Thiol) [58] |
Polycondensation |
Homopolymer |
Polyetheri |
115 |
Bis(p-Fluoroaryl)Ketone [13] |
Di/Polyol (Without Thiol) [58] |
Polycondensation |
Homopolymer |
Polyamide |
5 |
Lactam [5] |
Ring-Opening Chain Polymerization |
Homopolyme |
|
Polyamide |
7 |
Amino Acid [7] |
Polycondensation |
Homopolymer |
|
Polyamide |
109 |
Amino Acid [7] |
Amino Acid [7] |
Polycondensation |
|
Polyamide |
108 |
Di/Polycarboxylic Acid [52] |
Di/Polyamine [54] |
Polycondensation |
Homopolymer |
Polyimide |
110 |
Di/Polycyclic Anhydride [56] |
Primary Di/Polyamine [57] |
Polycondensation |
Homopolymer |
Polyurethane |
111 |
Di/Polyisocyanate [55] |
Di/Polyol [53] |
Polyaddition |
Homopolymer |
Polyoxazolidone |
113 |
Di/Polyepoxide [51] |
Di/Polyisocyanate [55] |
Polyaddition |
Homopolymer |
Table 4-9. For the unction “ole_copolym”
Defined polymer class, assigned polymeriztion reactions and corresponding monomer classes for the detailed olefin polymerization.
Polymer Class |
Polymerization Reaction |
Monomer Class |
|---|---|---|
ROMP |
1050 |
cycCH [1050] |
COC |
none |
cycCH [1050] + aliphCH [1052] |
rec:radi |
- |
acryl [1001], bEWole [1002], styryl [1003], allyl [1004], haloCH [1005], vinylester [1006], malei [1007], conjdiene [1020] |
rec:cati * |
- |
styryl [1003], vinylether [1030], tertcatCH [1031] |
rec:ani * |
- |
acryl [1001], styryl [1003], conjdiene [1020] |
rec:coord * |
ROMP, ROMPH, COC |
cycCH [1050], aliphCH [1052] (for COC) |
When all the components of the polymerization system correspond to the monomer class, it is recommended as a polymerization method.